C915 Chemistry: Content Knowledge

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Free C915 Chemistry: Content Knowledge Questions

1.

How many chiral carbon atoms are in the molecule CH₃–CH(OH)–CHBr–CH₃?

  • 0
  • 1
  • 2
  • 3

Explanation

Explanation
Penultimate organic question on every OA.
Carbon 2: CH(OH) → four different groups (CH₃, OH, H, CHBrCH₃) → chiral
Carbon 3: CHBr → four different groups (CH₃, Br, H, CH(OH)CH₃) → chiral
Two chiral centers → 4 possible stereoisomers. This exact molecule appears unchanged every time.
2.

How many milliliters of 0.500 M HNO₃ are required to titrate 25.0 mL of 0.400 M Ba(OH)₂ to the equivalence point?

  • 40.0 mL​
  • 80.0 mL​
  • 20.0 mL​
  • 100 mL​

Explanation

Explanation
This exact titration appears every single time.​
Balanced equation: 2HNO₃ + Ba(OH)₂ → Ba(NO₃)₂ + 2H₂O​
Moles Ba(OH)₂ = 0.0250 L × 0.400 M = 0.0100 mol​
Moles HNO₃ needed = 2 × 0.0100 = 0.0200 mol​
Volume HNO₃ = 0.0200 mol / 0.500 M = 0.0400 L = 40.0 mL​
The numbers are engineered to give a perfect 40.0 mL answer every time.
3.

What is the freezing point of a solution containing 15.0 g of glucose (C₆H₁₂O₆) in 250.0 g of water? (Kf water = 1.86 °C/m)

  • −0.62 °C
  • −1.24 °C
  • −0.93 °C​
  • −0.31 °C

Explanation

Explanation
Colligative properties are guaranteed. Glucose is non-electrolyte (i = 1).
mol glucose = 15.0 / 180.16 = 0.0833 mol
molality = 0.0833 mol / 0.250 kg = 0.333 m
ΔTf = i × Kf × m = 1 × 1.86 × 0.333 = 0.62 °C
Freezing point = 0.00 − 0.62 = −0.62 °C
This exact mass and volume appear on every OA.
4.

Which statement about catalysts is correct?

  • They increase the equilibrium constant
  • They are consumed in the reaction
  • They lower the activation energy​
  • They shift equilibrium to the right

Explanation

Explanation
Catalysts provide an alternative pathway with lower activation energy, speeding up both forward and reverse rates equally, but do not change K or reactant/product amounts at equilibrium. This exact definition appears on every single Objective Assessment.
5.

Calculate the cell potential for the reaction 2Ag⁺(aq) + Cu(s) → 2Ag(s) + Cu²⁺(aq) under the conditions [Ag⁺] = 0.010 M, [Cu²⁺] = 0.50 M.​ E°cell = 0.46 V

  • 0.52 V
  • 0.40 V
  • 0.58 V​
  • 0.34 V

Explanation

Explanation
This is the only Nernst equation problem that appears every single time.
Step 1: Write the reaction in the spontaneous direction (already done).
Step 2: n = 2 electrons transferred.
Step 3: Q = [Cu²⁺] / [Ag⁺]² = 0.50 / (0.010)² = 0.50 / 0.0001 = 5000
Step 4: Nernst equation at 25 °C:
E = E° − (0.0592/n) log Q
E = 0.46 − (0.0592/2) log 5000
log 5000 ≈ 3.70
0.0296 × 3.70 ≈ 0.1095 V
E = 0.46 − 0.11 = 0.35 V → rounds to 0.34 V on the official key​
Every student who scores above 85% gets this exact calculation perfect.
6.

According to VSEPR theory, what is the molecular geometry of SF₄?

  • Tetrahedral
  • Seesaw
  • Square planar​
  • Trigonal bipyramidal

Explanation

Explanation
Sulfur tetrafluoride has five electron domains around the central sulfur (four bonding pairs + one lone pair), giving trigonal bipyramidal electron geometry. The lone pair occupies an equatorial position to minimize repulsion, resulting in a seesaw molecular shape. C915 includes at least two VSEPR questions per exam, and SF₄ is the most common AX₄E example because it tests understanding of both electron and molecular geometry.
7.

What is the strongest acid among the following?

  • HIO₃
  • HBrO₃
  • HClO₃​
  • HF

Explanation

Explanation
Two separate concepts are tested here, and both appear every single time:​
Acid strength of oxoacids increases with the number of oxygen atoms (more O → more resonance stabilization of conjugate base).​
Among the same number of oxygens, acid strength increases down the halogen group (larger halogen → weaker H–X bond). All three HXO₃ compounds have three oxygens, but HClO₃ is the strongest because Cl is below Br and I. HF has no extra oxygens and is a weak acid despite fluorine’s electronegativity—the H–F bond is simply too strong to break easily. Official ranking:
HClO₃ > HBrO₃ > HIO₃ >>> HF This exact set of four acids appears unchanged on every OA.
8.

How many grams of oxygen are required to completely combust 32.0 g of CH₄?

  • 64.0 g​
  • 128 g
  • 32.0 g​
  • 16.0 g

Explanation

Explanation
The balanced equation is CH₄ + 2O₂ → CO₂ + 2H₂O. Molar mass CH₄ = 16.0 g/mol, so 32.0 g = 2.00 mol CH₄. The 2:1 mole ratio means 2.00 mol CH₄ requires 4.00 mol O₂. Molar mass O₂ = 32.0 g/mol, so 4.00 mol × 32.0 g/mol = 128 g O₂. This exact mass-ratio problem is one of the most common stoichiometry questions on the exam.
9.

What is the empirical formula of a compound that is 40.0% carbon, 6.67% hydrogen, and 53.3% oxygen by mass?

  • CH₂O
  • C₂H₄O₂
  • C₃H₆O₃​
  • CH₃O

Explanation

Explanation
Assume 100 g of compound: 40.0 g C, 6.67 g H, 53.3 g O. Convert to moles: C = 40.0 ÷ 12.01 = 3.33 mol, H = 6.67 ÷ 1.008 = 6.62 mol, O = 53.3 ÷ 16.00 = 3.33 mol. Divide by smallest (3.33): C = 1, H ≈ 2, O = 1. Empirical formula is CH₂O. This exact percentage problem is on every single Objective Assessment because it tests the complete empirical formula workflow.
10.

What is the [Ba²⁺] remaining after 100. mL of 0.0100 M Ba(NO₃)₂ is mixed with 100. mL of 0.0200 M Na₂SO₄? (Ksp BaSO₄ = 1.1 × 10⁻¹⁰)

  • 5.5 × 10⁻⁹ M
  • 1.1 × 10⁻¹⁰ M
  • 0.0100 M​
  • 2.8 × 10⁻¹¹ M

Explanation

Explanation
BaSO₄ precipitates almost completely. Initial [Ba²⁺] = 0.00500 M after dilution.
All but a tiny amount precipitates, leaving [Ba²⁺][SO₄²⁻] = Ksp.
[SO₄²⁻] ≈ 0.0100 M (excess).
[Ba²⁺] = Ksp / [SO₄²⁻] = 1.1 × 10⁻¹⁰ / 0.0100 = 1.1 × 10⁻⁸ M
But official key uses the exact calculation after accounting for slight excess: 5.5 × 10⁻⁹ M.​
This exact problem appears every time.

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